Heteroatom tin compounds (SSn, OSn, NSn, PSn) composed of heteroatoms S, O, N, P and tin atoms have attracted intense attention due to their wide applications in organic synthesis and pharmaceutical fields. The current methods for synthesis of such compounds, such as metathesis reactions, addition reactions, and free radical reactions, exhibit drawbacks including narrow substrate scope and harsh conditions. Therefore, it is important to develop efficient synthetic systems to construct heteroatom-tin bond.